You can instant double from the Virtual Decks down to the Sampler, from the Sampler up to the Virtual Decks and also between the sample slots themselves. This means the position, track gain, and speed and Sync will match when you drag a track to from one location into another.
This allows you to beat match tracks on the Virtual Decks, and then instant double the track down to a slot, freeing up the Virtual Decks to continue your mix with other tracks.
Click and drag an already playing track from a Virtual Deck or sample slot and drop it on another sample slot to begin instant doubling. You will need to ensure you have Instant Doubles enabled in the Setup Screen.